Preferred Orientation in Microstructures
نویسنده
چکیده
The microstructures of eutectics between compounds were studied for systems MnO-MnS, NaCl-NaF, NaBr-NaF, LiF-NaF, and FeO-FeS. With the exception of FeS, all the compounds had the NaC1-type structure. In the systems having only NaC1-type structures, the lamellas of the two eutectic phases had matching crystal orientations. There was less consistency among the eutectic systems, however, than between the phase pairs. The crystal growth directions in all five systems were different, and no more than two of the systems had the same set of interfacial planes. One must conclude that the two phases within a eutectic of compounds do not solidify independently of one another. It is suggested that the two phases of an NaC1-type eutectic pair crystallize as a “single” ionic crystal with imperfections present to accommodate the dimensional mismatch.
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